Alcohols and Phenols MCQs [Organic Chemistry]
MCQs-based questions and answers on Alcohols and Phenols in organic chemistry.
Which of the mentioned compounds should be least soluble in water?
- Chlorobenzene
- Ethanol
- Benzoic acid
- Phenol
Question’s Answer: Chlorobenzene
Which of the mentioned is most acidic?
- C3H7OH
- C2H5OH
- CH3OH
- H₂O
Question’s Answer: CH3OH
Which of the mentioned reagent cannot be used to detect the phenolic group?
- Neutral FeCl3
- Br₂/H2O
- NaOH solution
- I2/NaOH
Question’s Answer: I2/NaOH
An aromatic compound has a molecular formula C7H8O. How many isomers are possible for this compound?
- 3
- 5
- 4
- 6
Question’s Answer: 5
Which of the mentioned is a wood alcohol?
- Ethanol
- Metahnol
- Propanol
- None of A, B, and C
Question’s Answer: Metahnol
Which of the mentioned alcohol is produced from fermentation of sugars?
- Ethanol
- Metahnol
- Propanol
- None of A, B, and C
Question’s Answer: Ethanol
The composition of rectified spirit is
- 90% Ethanol
- 100% Ethanol
- 95% Ethanol
- None of A, B, and C
Question’s Answer: 95% Ethanol
Carbolic acid is ____.
- Salol
- Phenyl benzoate
- Phenol
- Phenyl acetate
Question’s Answer: Phenol
Which of the mentioned is trihydric phenol?
- Resorcinol
- Phloroglucinol
- p-Cresol
- Catechol
Question’s Answer: Phloroglucinol
Grignard reagent reacts with aldehydes and ketones to form.
- Aldehydes
- Ketones
- Alcohols
- Amines
Question’s Answer: Alcohols
There are total _________ primary alcohols that are possible for C4H9OH?
- 3
- 4
- 1
- 2
Question’s Answer: 2
What is an isomer of ethanol?
- Methanol
- Ethanal
- Methoxy methane
- Ethoxy ethane
Question’s Answer: Methoxy methane
n-Propyl alcohol and iso-propyl alcohol is an example of which of the following?
- Position isomerism
- Chain isomerism
- Metamerism
- Tautomersim
Question’s Answer: Position isomerism
Reduction of aldehydes either by hydrogenation, or in the presence of metal catalyst such as Ni, Pt. or Pd gives
- Alcohols
- Carboxylic acid
- Amines
- Amides
Question’s Answer: Alcohols
Ethyl acetate reacts with Grignard reagent to form
- Secondary alcohol
- Tertiary alcohol
- Primary alcohol and acid
- Acid
Question’s Answer: Tertiary alcohol
In which of the mentioned group, each member gives a positive iodoform test?
- Methanol, ethanol, propanone
- Ethanol, isopropyl alcohol, methanol
- Propanal, 2-propanol, propanone
- Ethanol, ethanal, isopropyl alcohol
Question’s Answer: Ethanol, ethanal, isopropyl alcohol
The reaction of formaldehyde and Grignard reagent followed by acidification gives
- Aldehyde
- Primary alcohol
- Carboxylic acid
- Ketone
Question’s Answer: Primary alcohol
The enzyme that converts sucrose to glucose and fructose is called
- Zymase
- Diastase
- Maltase
- Invertase
Question’s Answer: Invertase
The enzyme that converts starch to maltose is called
- Maltase
- Diastase
- Invertase
- Zymase
Question’s Answer: Maltase
Which of the mentioned alcohol is least soluble in water?
- Methanol
- n-Butyl alcohol
- n-Propyl alcohol
- Ethanol
Question’s Answer: n-Butyl alcohol
What is the order of reactivity of alcohols with sodium metal?
- 3°>2″>1°
- 2°>3°>1°
- 1°>2°>3°
- None of A, B, and C
Question’s Answer: 1°>2°>3°
Phenol on heating with alc.KOH and chloroform undergoes __.
- Kolbe reaction
- Rosenmund reaction
- Cannizzaro reaction
- Reimer-Tiemann reaction
Question’s Answer: Reimer-Tiemann reaction
Which of the mentioned will be readily attacked by an electrophile?
- Phenol
- Benzene
- Chlorophenol
- Toluene
Question’s Answer: Phenol
Which of the mentioned statements regarding phenols is not correct?
- Phenols are soluble in both aqueous t NaOH and aqueous sodium hydrogen carbonate
- Phenols are weaker acids than carboxylic acids
- Phenols are stronger acids than water and alcohols
- Phenoxides ions are more stable than the corresponding phenols
Question’s Answer: Phenols are soluble in both aqueous t NaOH and aqueous sodium hydrogen carbonate
Phenol on reaction with ethanoic anhydride in the presence of sodium ethanoate gives
- Phenyl benzoate
- Ethyl benzoate
- Phenyl methyl ether
- Phenyl ethanoate
Question’s Answer: Phenyl ethanoate
Each of the following when present at para position decreases the acidic strength of phenol excluding which of the following?
- -NH2
- CH3O-
- -CI
- CH3–
Question’s Answer: -CI
Which of the mentioned compounds is formed by catalytic reduction of phenol?
- Benzene
- Cyclohexane
- Cyclohexanol
- Benzyl alcohol
Question’s Answer: Cyclohexanol
Glycerol on dehydration produces __.
- Acrolein
- Allyl alcohol
- CHOH=C=CHOH
- CHO-CHOH-CH2OH
Question’s Answer: Acrolein
Phenol on treatment with Con. HNO3 gives which of the following?
- o-Nitrophenol
- 2,4,6 Trinitrophenol
- o-and p-Nitrophenol
- p-Nitrophenol
Question’s Answer: 2,4,6 Trinitrophenol
Treatment of phenol with cold dilute nitric acid gives
- Only o-nitro phenol
- Mixture of o-and p-nitro phenol
- 2,4,6-Trinitro phenol
- Only p-nitro phenol base
Question’s Answer: Mixture of o-and p-nitro phenol
Which of the mentioned is the strongest base?
- Ethoxide
- Methoxide
- Ter-butoxide
- Iso-propoxide
Question’s Answer: Ter-butoxide
Which of the mentioned is the strongest base
- CH3–
- OR–
- OH–
- NH2–
Question’s Answer: CH3–
What is the suitable reagent for dehydration of alcohol?
- PCI5
- CaCl2
- Al2O3
- NaCl
Question’s Answer: Al2O3
Which is the best reagent for producing an alkyl chloride from an alcohol?
- SOCI2
- PCl3
- PCl5
- HCI
Question’s Answer: SOCI2
On oxidation, which of the following gives ketone?
- Primary alcohol
- Tertiary alcohol
- Secondary Alcohol
- All of A, B, and C
Question’s Answer: Secondary Alcohol
What is formed when a primary alcohol undergoes catalytic dehydrogenation?
- Ketone
- Aldehyde
- Alkene
- Acid
Question’s Answer: Ketone
Alcohols can be taken from all methods excluding which of the following?
A Hydroboration-oxidation
- Oxymercuration-demerucuration
- Fermentation of starch
- Reduction of carbonyl compounds with Zn-Hg/HCl
Question’s Answer: Reduction of carbonyl compounds with Zn-Hg/HCl
Alkyl halides react with aqueous NaOH to form ______ .
- Alcohols
- Ketones
- Amines
- Aldehydes
Question’s Answer: Alcohols
The acid-catalyzed addition of water to an alkene produces which of the following?
- Aldehydes
- Alcohols
- Amines
- Ketones
Question’s Answer: Alcohols
What is the increasing reactivity of CH3OH, CH3CH2OH, CH3CH2CH2OH and (CH3)2CHOH towards sodium metal?
- CH3OH < CH3CH₂OH < CH3CH2CH₂OH < (CH3)2CHOH
- (CH3)2CHOH < CH3CH2OH < CH3CH2CH2OH < CH3OH
- CH3CH2CH2OH < (CH3)2CHOH < CH3CH₂OH < CH3OH
- (CH3)2CHOH < CH3CH2CH2OH < CH3CH2OH < CH3OH
Question’s Answer: (CH3)2CHOH < CH3CH2CH2OH < CH3CH2OH < CH3OH
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