Ethanol [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman Shamil | Last updated: February 3, 2024

Chemical formula of ethanol  is C2H5OH.

Physical Properties of Ethanol:

Properties Details
AppearanceColorless liquid
Boiling Point78.37°C
Density0.789 g/cm³ at 20°C
FlammabilityHighly flammable
Flash Point13°C
Melting Point-114.14°C
Molecular FormulaC2H5OH
Molecular Weight46.07 g/mol
OdorPleasant, characteristic odor
Refractive Index1.361 at 20°C
SolubilitySoluble in water and many organic solvents
Vapor Pressure59.2 mmHg at 20°C
Viscosity1.2 mPa·s at 20°C

Chemical Properties of Ethanol:

Properties Details
AcidityWeakly acidic; forms ethoxide ions in the presence of bases
Chemical FormulaC2H5OH
CombustionBurns in the presence of oxygen to produce carbon dioxide and water
DehydrationCan undergo dehydration to form ethene (ethylene) gas
EsterificationCan form esters through reactions with carboxylic acids
FermentationCan be produced through the fermentation of sugars by yeast
HalogenationCan undergo halogenation reactions, e.g., with chlorine or bromine
Molecular Weight46.07 g/mol
OxidationEthanol can be oxidized to acetaldehyde and further to acetic acid
ReactivityReacts with acids, alkalis, and oxidizing agents
ToxicityEthanol is toxic and can cause harmful effects on the body when consumed in large amounts

Reaction of ethanol

Alkali metal

Alkali metalReaction with ethanol
Lithium (Li)2Li + 2C2H5OH convert to 2C2H5OLi + H2
Sodium (Na)2Na + 2C2H5OH convert to 2C2H5ONa + H2
Potassium (K)2K + 2C2H5OH convert to 2C2H5OK + H2
Rubidium (Rb)2Rb + 2C2H5OH convert to 2C2H5ORb + H2
Cesium (Cs)2Cs + 2C2H5OH convert to 2C2H5OCs + H2

 

Alkaline earth metal

 

 

Alkaline earth metalReaction with ethanolProduct name
BerylliumBe + 2C2H5OH convert to Be(OC2H5)2 + H2Beryllium ethoxide
MagnesiumMg + 2C2H5OH convert to Mg(OC2H5)2 + H2Magnesium ethoxide
Calcium Ca + 2C2H5OH convert to Ca(OC2H5)2 + H2Calcium ethoxide
StrontiumSr + 2C2H5OH convert to Sr(OC2H5)2 + H2Strontium ethoxide
BariumBa + 2C2H5OH convert to Ba(OC2H5)2 + H2Barium ethoxide

 

Transition metal

Transition metalReaction with ethanolProduct(s)
Iron (Fe)2Fe + 6C2H5OH convert to 2Fe(OC2H5)3 + 3H2Iron(III) ethoxide
Copper (Cu)2Cu + 4C2H5OH convert to 2CuOC2H5 + 3H2Copper(I) ethoxide
Silver (Ag)4Ag + 4C2H5OH convert to 4C2H5OAg + 2H2 + O2Silver ethoxide
Platinum (Pt)Pt + 4C2H5OH convert to Pt(OC2H5)2 + 2H2Platinum(II) ethoxide

 

Post-transition metal

Post-transition metalReaction with ethanolProduct(s)
Aluminum (Al)2Al + 6C2H5OH convert to 2Al(OC2H5)3 + 3H2Aluminum ethoxide
Zinc (Zn)Zn + 2C2H5OH convert to Zn(OC2H5)2 + H2Zinc ethoxide
Tin (Sn)Sn + 4C2H5OH convert to Sn(OC2H5)4 + 2H2Tin ethoxide
Lead (Pb)Pb + 2C2H5OH convert to Pb(OC2H5)2 + H2Lead ethoxide

 

Non-metal

Non-metalReaction with ethanolProduct(s)
Carbon (C)C2H5OH convert to CO + 3H2Carbon monoxide and  hydrogen gas
Hydrogen (H)C2H5OH + H2 convert to CH3CHO + H2OAcetaldehyde and  water
Chlorine (Cl)C2H5OH + Cl2 convert to C2H5Cl + HClChloroethane and  hydrogen chloride gas
Oxygen (O)C2H5OH + 1/2O2 convert to CH3CHO + H2OAcetaldehyde and  water