Ethanol [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman | Last updated: February 3, 2024

Chemical formula of ethanol  is C2H5OH.

Physical Properties of Ethanol:

Properties Details
Appearance Colorless liquid
Boiling Point 78.37°C
Density 0.789 g/cm³ at 20°C
Flammability Highly flammable
Flash Point 13°C
Melting Point -114.14°C
Molecular Formula C2H5OH
Molecular Weight 46.07 g/mol
Odor Pleasant, characteristic odor
Refractive Index 1.361 at 20°C
Solubility Soluble in water and many organic solvents
Vapor Pressure 59.2 mmHg at 20°C
Viscosity 1.2 mPa·s at 20°C

Chemical Properties of Ethanol:

Properties Details
Acidity Weakly acidic; forms ethoxide ions in the presence of bases
Chemical Formula C2H5OH
Combustion Burns in the presence of oxygen to produce carbon dioxide and water
Dehydration Can undergo dehydration to form ethene (ethylene) gas
Esterification Can form esters through reactions with carboxylic acids
Fermentation Can be produced through the fermentation of sugars by yeast
Halogenation Can undergo halogenation reactions, e.g., with chlorine or bromine
Molecular Weight 46.07 g/mol
Oxidation Ethanol can be oxidized to acetaldehyde and further to acetic acid
Reactivity Reacts with acids, alkalis, and oxidizing agents
Toxicity Ethanol is toxic and can cause harmful effects on the body when consumed in large amounts

Reaction of ethanol

Alkali metal

Alkali metal Reaction with ethanol
Lithium (Li) 2Li + 2C2H5OH convert to 2C2H5OLi + H2
Sodium (Na) 2Na + 2C2H5OH convert to 2C2H5ONa + H2
Potassium (K) 2K + 2C2H5OH convert to 2C2H5OK + H2
Rubidium (Rb) 2Rb + 2C2H5OH convert to 2C2H5ORb + H2
Cesium (Cs) 2Cs + 2C2H5OH convert to 2C2H5OCs + H2

 

Alkaline earth metal

 

 

Alkaline earth metal Reaction with ethanol Product name
Beryllium Be + 2C2H5OH convert to Be(OC2H5)2 + H2 Beryllium ethoxide
Magnesium Mg + 2C2H5OH convert to Mg(OC2H5)2 + H2 Magnesium ethoxide
Calcium  Ca + 2C2H5OH convert to Ca(OC2H5)2 + H2 Calcium ethoxide
Strontium Sr + 2C2H5OH convert to Sr(OC2H5)2 + H2 Strontium ethoxide
Barium Ba + 2C2H5OH convert to Ba(OC2H5)2 + H2 Barium ethoxide

 

Transition metal

Transition metal Reaction with ethanol Product(s)
Iron (Fe) 2Fe + 6C2H5OH convert to 2Fe(OC2H5)3 + 3H2 Iron(III) ethoxide
Copper (Cu) 2Cu + 4C2H5OH convert to 2CuOC2H5 + 3H2 Copper(I) ethoxide
Silver (Ag) 4Ag + 4C2H5OH convert to 4C2H5OAg + 2H2 + O2 Silver ethoxide
Platinum (Pt) Pt + 4C2H5OH convert to Pt(OC2H5)2 + 2H2 Platinum(II) ethoxide

 

Post-transition metal

Post-transition metal Reaction with ethanol Product(s)
Aluminum (Al) 2Al + 6C2H5OH convert to 2Al(OC2H5)3 + 3H2 Aluminum ethoxide
Zinc (Zn) Zn + 2C2H5OH convert to Zn(OC2H5)2 + H2 Zinc ethoxide
Tin (Sn) Sn + 4C2H5OH convert to Sn(OC2H5)4 + 2H2 Tin ethoxide
Lead (Pb) Pb + 2C2H5OH convert to Pb(OC2H5)2 + H2 Lead ethoxide

 

Non-metal

Non-metal Reaction with ethanol Product(s)
Carbon (C) C2H5OH convert to CO + 3H2 Carbon monoxide and  hydrogen gas
Hydrogen (H) C2H5OH + H2 convert to CH3CHO + H2O Acetaldehyde and  water
Chlorine (Cl) C2H5OH + Cl2 convert to C2H5Cl + HCl Chloroethane and  hydrogen chloride gas
Oxygen (O) C2H5OH + 1/2O2 convert to CH3CHO + H2O Acetaldehyde and  water

 

 

 

 

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