Calcium oxide [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman | Last updated: February 3, 2024

Chemical formula of calcium oxide is CaO.

Physical Properties of Calcium Oxide (CaO):

Properties Details
Appearance White, crystalline solid
Boiling Point Decomposes at high temperatures (above 2,572°C or 4,662°F)
Crystal Structure Cubic
Density 3.34 g/cm³
Electrical Conductivity Insulator (non-conductive)
Melting Point 2,572°C (4,662°F)
Odor Odorless
Solubility Insoluble in water
Specific Heat Capacity 40.0 J/(mol·K)
State of Matter Solid
Thermal Conductivity Low

Chemical Properties of Calcium Oxide (CaO):

Properties Details
Acid-Base Properties Strong base; reacts with acids to form calcium salts
Chemical Formula CaO
Chemical Reaction with Water Reacts vigorously with water to form calcium hydroxide (Ca(OH)₂)
Hygroscopicity Absorbs moisture from the air, forming calcium hydroxide and becoming slaked
Oxidation State Calcium exhibits an oxidation state of +2 in calcium oxide
Reactivity Highly reactive; reacts exothermically with acids and can cause burns
Reactivity with CO₂ Reacts with carbon dioxide (CO₂) in the air to form calcium carbonate (CaCO₃)

Reaction Of Calcium Oxide with Alkali Metal

Alkali Metal Chemical Symbol Reaction with Calcium Oxide
Lithium Li CaO + 2Li → Li2O + Ca
Sodium Na CaO + 2Na → Na2O + Ca
Potassium K CaO + 2K → K2O + Ca
Rubidium Rb CaO + 2Rb → Rb2O + Ca
Cesium Cs CaO + 2Cs → Cs2O + Ca

Reaction Of Calcium Oxide with Alkaline Earth Metal

Alkaline Earth Metal Chemical Symbol Reaction with Calcium Oxide
Beryllium Be No reaction
Magnesium Mg CaO + Mg → MgO + Ca
Calcium Ca No reaction
Strontium Sr CaO + Sr → SrO + Ca
Barium Ba CaO + Ba → BaO + Ca
Radium Ra CaO + Ra → RaO + Ca

Reaction Of Calcium Oxide with Transition Metal

Transition Metal Chemical Symbol Reaction with Calcium Oxide
Scandium Sc No reaction
Titanium Ti CaO + Ti → TiO2 + Ca
Vanadium V CaO + V → V2O5 + Ca
Chromium Cr CaO + Cr → Cr2O3 + Ca
Manganese Mn CaO + Mn → MnO + Ca
Iron Fe CaO + Fe → FeO + Ca
Cobalt Co No reaction
Nickel Ni CaO + Ni → NiO + Ca
Copper Cu CaO + 2Cu → 2CuO + Ca
Zinc Zn CaO + Zn → ZnO + Ca
Silver Ag CaO + 2Ag → Ag2O + Ca
Gold Au No reaction
Mercury Hg CaO + Hg → HgO + Ca

Reaction Of Calcium Oxide with Non-Transition Metal

Non-Transition Metal Chemical Symbol Reaction with Calcium Oxide
Hydrogen H CaO + H2O → Ca(OH)2
Helium He No reaction
Carbon C CaO + C → CaC2 + CO
Nitrogen N No reaction
Oxygen O 2CaO + O2 → 2CaO2
Fluorine F CaO + 2F2 → CaF2 + O2
Neon Ne No reaction
Chlorine Cl CaO + 2Cl2 → CaCl2 + CO2
Argon Ar No reaction
Bromine Br CaO + 2Br2 → CaBr2 + CO2
Iodine I CaO + 2I2 → CaI2 + CO2
Xenon Xe No reaction

Reaction Of Calcium Oxide with Non-Metal

Non-Metal Chemical Symbol Reaction with Calcium Oxide
Hydrogen H CaO + H2O → Ca(OH)2
Helium He No reaction
Carbon C CaO + C → CaC2 + CO
Nitrogen N CaO + 2N → Ca3N2
Oxygen O 2CaO + O2 → 2CaO2
Fluorine F CaO + 2F2 → CaF2 + O2
Neon Ne No reaction
Chlorine Cl CaO + 2Cl2 → CaCl2 + CO2
Argon Ar No reaction
Bromine Br CaO + 2Br2 → CaBr2 + CO2
Iodine I CaO + 2I2 → CaI2 + CO2
Xenon Xe No reaction
Phosphorus P CaO + P4 → Ca3P2 + 2Ca
Sulfur S CaO + S → CaS + CO2
Selenium Se CaO + Se → CaSe + CO2
Bromine Br CaO + 2Br2 → CaBr2 + CO2
Iodine I CaO + 2I2 → CaI2 + CO2

Reaction Of Calcium Oxide with Metalloid

Metalloid Chemical Symbol Reaction with Calcium Oxide
Boron B CaO + B2O3 → CaB4O7
Silicon Si CaO + SiO2 → CaSiO3
Germanium Ge CaO + GeO2 → CaGeO3
Arsenic As CaO + As2O3 → Ca3(AsO4)2
Antimony Sb CaO + Sb2O3 → Ca3Sb2O7
Tellurium Te CaO + TeO2 → CaTeO3
Polonium Po CaO + PoO2 → CaPoO2
Boron B CaO + 2B → CaB2 + O2
Silicon Si 2CaO + Si → Ca2SiO4
Germanium Ge 2CaO + Ge → Ca2GeO4
Arsenic As 2CaO + As → Ca3As2O8
Antimony Sb 2CaO + Sb → Ca3Sb2O8
Tellurium Te 2CaO + Te → CaTeO3 + Ca
Polonium Po No reaction

Reaction Of Calcium Oxide with lanthanides

Element Reaction with Calcium Oxide
Cerium CeO2 + CaO → CaCeO3
Europium Eu2O3 + 3CaO → 2EuCaO3
Lutetium Lu2O3 + 3CaO → 2LuCaO3
Gadolinium Gd2O3 + 3CaO → 2GdCaO3
Lanthanum La2O3 + 3CaO → 2LaCaO3

Reaction Of Calcium Oxide with actinides

Element Reaction with Calcium Oxide
Uranium U3O8 + 6CaO → 3UO2·2CaO + 2Ca3UO6
Plutonium PuO2 + 2CaO → PuCa2O4
Americium AmO2 + 2CaO → AmCa2O4
Thorium ThO2 + 2CaO → Ca2ThO4
Curium Cm2O3 + 3CaO → 2CmCaO3

 

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