Iron oxide [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman Shamil | Last updated: February 3, 2024

chemical formula of iron oxide are given below

  • iron(II) oxide (FeO)
  • iron(III) oxide (Fe2O3)

Physical Properties of Iron Oxide:

PropertyDetails
AppearancePowdery or crystalline solid
Boiling PointVaries depending on the type of iron oxide
ColorReddish-brown or black
ConductivityPoor electrical and thermal conductivity
Crystal StructureVaries depending on the type of iron oxide
DensityVaries depending on the type of iron oxide
HardnessVaries depending on the type of iron oxide
Magnetic PropertiesExhibits ferromagnetic properties
Melting PointVaries depending on the type of iron oxide
OdorOdorless
SolubilityInsoluble in water and most solvents
Specific GravityVaries depending on the type of iron oxide
StateSolid

Chemical Properties of Iron Oxide:

PropertyDetails
Acid/Base PropertiesCan act as a weak Lewis acid in some reactions
CombustibilityNon-combustible
CorrosionIron oxides can cause corrosion of metals and alloys
HygroscopicityIron oxide powders can absorb moisture from the air
Oxidation/ReductionIron(III) oxide can be reduced to iron metal
Photocatalytic ActivityCertain types of iron oxide can exhibit photocatalytic properties
Reaction with WaterIron(III) oxide reacts slowly with water to form iron(III) hydroxide
Reactivity with AcidsIron oxides react with strong acids to form salts
Reactivity with BasesGenerally inert, does not react with bases
Reactivity with Other MetalsCan undergo redox reactions with other metals
StabilityStable under normal conditions

Reactions of iron oxide with Alkali Metal

Alkali MetalReaction Equation 
Lithium (Li)2Li + Fe2O3   react and convert into  2Li2O + 2Fe
Sodium (Na)4Na + Fe2O3   react and convert into  2Na2O + 2Fe
Potassium (K)4K + Fe2O3   react and convert into  2K2O + 2Fe
Rubidium (Rb)4Rb + Fe2O3   react and convert into  2Rb2O + 2Fe
Cesium (Cs)4Cs + Fe2O3   react and convert into  2Cs2O + 2Fe

Reactions of iron oxide with Alkaline Earth Metal

Alkaline Earth MetalReaction Equation 
Beryllium (Be)No product formed
Magnesium (Mg)3Mg + Fe2O3   react and convert into  3MgO + 2Fe
Calcium (Ca)3Ca + Fe2O3   react and convert into  3CaO + 2Fe
Strontium (Sr)3Sr + Fe2O3   react and convert into  3SrO + 2Fe
Barium (Ba)3Ba + Fe2O3   react and convert into  3BaO + 2Fe
Radium (Ra)No product formed

Reactions of iron oxide with Transition Metal

Transition MetalReaction Equation 
Scandium (Sc)No product formed
Titanium (Ti)No product formed
Vanadium (V)No product formed
Chromium (Cr)No product formed
Manganese (Mn)3Mn + Fe2O3   react and convert into  3MnO + 2Fe
Iron (Fe)No product formed
Cobalt (Co)No product formed
Nickel (Ni)No product formed
Copper (Cu)3Cu + Fe2O3    react and convert into  3CuO + 2Fe
Zinc (Zn)No product formed
Yttrium (Y)No product formed
Zirconium (Zr)No product formed
Niobium (Nb)No product formed
Molybdenum (Mo)No product formed
Technetium (Tc)No product formed
Ruthenium (Ru)No product formed
Rhodium (Rh)No product formed
Palladium (Pd)No product formed
Silver (Ag)3Ag + Fe2O3   react and convert into  3Ag2O + 2Fe
Cadmium (Cd)No product formed
Hafnium (Hf)No product formed
Tantalum (Ta)No product formed
Tungsten (W)No product formed
Rhenium (Re)No product formed
Osmium (Os)No product formed
Iridium (Ir)No product formed
Platinum (Pt)No product formed
Gold (Au)3Au + Fe2O3   react and convert into  3Au2O3 + 2Fe
Mercury (Hg)No product formed
Rutherfordium (Rf)No product formed
Dubnium (Db)No product formed
Seaborgium (Sg)No product formed
Bohrium (Bh)No product formed
Hassium (Hs)No product formed
Meitnerium (Mt)No product formed
Darmstadtium

Reactions of iron oxide with Non-Transition Metal

Non-Transition MetalReaction Equation 
Aluminum (Al)2Al + Fe2O3   react and convert into  Al2O3 + 2Fe
Gallium (Ga)2Ga + Fe2O3   react and convert into  Ga2O3 + 2Fe
Indium (In)2In + Fe2O3   react and convert into  In2O3 + 2Fe
Tin (Sn)2Sn + Fe2O3   react and convert into  SnO2 + 2Fe
Thallium (Tl)2Tl + Fe2O3   react and convert into  Tl2O3 + 2Fe
Lead (Pb)2Pb + Fe2O3   react and convert into  PbO + PbFe2O4
Bismuth (Bi)No product formed
Polonium (Po)No product formed

Reactions of iron oxide with Non-Metal

Non-MetalReaction Equation 
Hydrogen (H2)3H2 + Fe2O3   react and convert into  Fe2O3  + 3H2O
Carbon (C)No product formed
Nitrogen (N2)No product formed
Oxygen (O2)No product formed
Fluorine (F2)No product formed
Phosphorus (P4)No product formed
Sulfur (S8)No product formed
Chlorine (Cl2)No product formed
Bromine (Br2)No product formed
Iodine (I2)No product formed
Noble GasesNo product formed