Magnesium oxide [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman Shamil | Last updated: February 3, 2024

The chemical formula of magnesium oxide is MgO.

Physical Properties of Magnesium Oxide

Properties Details
AppearanceWhite, odorless solid
Boiling Point3,600°C (6,512°F)
Crystal StructureCubic
Density3.58 g/cm³
Melting Point2,852°C (5,166°F)
SolubilityInsoluble in water
StateSolid

Chemical Properties of Magnesium Oxide

Properties Details
Chemical FormulaMgO
Chemical Reaction with AcidMagnesium oxide reacts with acids to produce a salt and water
CombustibilityNon-combustible
HygroscopicityAbsorbs moisture from the air
OxidationMagnesium oxide readily undergoes oxidation reactions
ReactivityHighly reactive with acids and forms salts
StabilityChemically stable under normal conditions

Reaction of magnesium oxide with Alkali Metal

Alkali MetalReaction with Magnesium Oxide
Lithium (Li)Li2O + MgO → 2LiMgO
Sodium (Na)Na2O + MgO → NaMg2O2
Potassium (K)K2O + MgO → K2MgO2
Rubidium (Rb)Rb2O + MgO → Rb2MgO2
Cesium (Cs)Cs2O + MgO → Cs2MgO2
Francium (Fr)Fr2O + MgO → Fr2MgO2

 

 

 

Alkali MetalReaction with Magnesium Oxide
Lithium (Li)Li2O + MgO → 2LiMgO
Sodium (Na)Na2O + MgO → NaMg2O2
Potassium (K)K2O + MgO → K2MgO2
Rubidium (Rb)Rb2O + MgO → Rb2MgO2
Cesium (Cs)Cs2O + MgO → Cs2MgO2
Francium (Fr)Fr2O + MgO → Fr2MgO2

Reaction of magnesium oxide with Transition Metal

Transition MetalReaction with Magnesium Oxide
Iron (Fe)3FeO + 2MgO → Fe3O4 + 2MgO
Copper (Cu)2CuO + MgO → 2CuO·MgO
Zinc (Zn)ZnO + MgO → ZnMgO
Nickel (Ni)NiO + MgO → NiMgO
Cobalt (Co)CoO + MgO → CoMgO
Manganese (Mn)Mn3O4 + 4MgO → 3MgMnO2

Reaction of magnesium oxide with Non-Transition Metal

Non-Transition MetalReaction with Magnesium Oxide
Aluminum (Al)Al2O3 + 2MgO → 2MgAl2O4
Silicon (Si)SiO2 + 2MgO → Mg2SiO4
Carbon (C)C + MgO → Mg + CO
Phosphorus (P)P4O10 + 10MgO → 5Mg2P2O7
Sulfur (S)SO2 + MgO → MgSO3
Chlorine (Cl)2MgO + Cl2 → MgCl2 + MgOCl2

Reaction of magnesium oxide with Non-Metal

Non-MetalReaction with Magnesium Oxide
Hydrogen (H)MgO + H2 → Mg + H2O
Carbon (C)MgO + C → Mg + CO
Nitrogen (N)MgO + 2NH3 → Mg3N2 + 2H2O
Oxygen (O)2MgO + O2 → 2MgO2
Fluorine (F)MgO + 2F2 → MgF2 + OF2
Chlorine (Cl)MgO + 2Cl2 → MgCl2 + Cl2O

Reaction of magnesium oxide with Metalloid

MetalloidReaction with Magnesium Oxide
Boron (B)B2O3 + 3MgO → Mg3B2O6
Silicon (Si)SiO2 + 2MgO → Mg2SiO4
Germanium (Ge)GeO2 + MgO → MgGeO3