Calcium chloride [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman | Last updated: February 3, 2024

The chemical formula for calcium chloride is CaCl2.

Physical Properties of Calcium Chloride:

Properties Details
Appearance White, crystalline powder or flakes
Boiling Point 1,935 °C (3,515 °F)
Conductivity Conducts electricity when dissolved in water
Density 2.15 g/cm³
Hygroscopicity Hygroscopic (absorbs moisture from the air)
Melting Point 772 °C (1,422 °F)
Odor Odorless
Solubility in Water Highly soluble, forms a clear, colorless solution
State of Matter Solid at room temperature

Chemical Properties of Calcium Chloride:

Properties Details
Chemical Formula CaCl₂
Corrosiveness Corrosive to some metals, such as aluminum
Dehydration Can act as a desiccant by removing water from substances
Deliquescence Absorbs water from the air and forms a solution
Exothermic Heat Generation Generates heat when mixed with water
Freezing Point Depression Lowers the freezing point of water when used as a de-icer
Ionization Dissociates into calcium ions (Ca²⁺) and chloride ions (Cl⁻)
Reaction with Water Exothermic reaction, dissolves readily in water
Reactivity Reactive with certain metals and organic compounds

Reaction of calcium chloride with Alkaline Earth Metal

Alkaline Earth Metal Reaction with Calcium Chloride Reaction equation
Beryllium (Be)   no product
Magnesium (Mg) Formation of magnesium chloride CaCl2 + Mg   react and convert into  MgCl2 + Ca
Calcium (Ca)   no product
Strontium (Sr) Formation of strontium chloride CaCl2+ Sr   react and convert into  SrCl2 + Ca
Barium (Ba) Formation of barium chloride CaCl2+ Ba   react and convert into  BaCl2 + Ca
Radium (Ra) Formation of radium chloride (radioactive product) CaCl2+ Ra   react and convert into  RaCl2 + Ca

Reaction of calcium chloride with Non-Transition Metal

Non-Transition Metal Reaction with Calcium Chloride Reaction equation
Hydrogen (H) Formation of hydrogen chloride gas CaCl2+ 2HCl   react and convert into  CaCl2 + H2(g)
Boron (B)   no product
Carbon (C) Formation of calcium carbide and carbon dioxide gas CaCl2+ 2C   react and convert into  CaC2 + 2Cl2(g) + CO2(g)
Nitrogen (N)   no product
Oxygen (O) Formation of calcium oxide and chlorine gas CaCl2+ O2   react and convert into  2CaO + 2Cl2(g)
Fluorine (F) Formation of calcium fluoride CaCl2+ 2HF   react and convert into  CaF2 + 2HCl
Neon (Ne)   no product

Reaction of calcium chloride with Non-Metal

Non-Metal Reaction with Calcium Chloride Reaction equation
Hydrogen (H) Formation of hydrogen chloride gas CaCl2+ 2HCl   react and convert into  CaCl2 + H2(g)
Carbon (C) Formation of calcium carbide and carbon dioxide gas CaCl2+ 2C   react and convert into  CaC2 + 2Cl2(g) + CO2(g)
Nitrogen (N)   no product
Oxygen (O) Formation of calcium oxide and chlorine gas CaCl2+ O2   react and convert into  2CaO + 2Cl2(g)
Fluorine (F) Formation of calcium fluoride CaCl2+ 2HF   react and convert into  CaF2 + 2HCl
Chlorine (Cl)   no product  (both are already chloride compounds)
Bromine (Br) Formation of calcium bromide CaCl2+ 2HBr   react and convert into  CaBr2 + 2HCl
Iodine (I) Formation of calcium iodide CaCl2 + 2KI   react and convert into  CaI2 + 2KCl
Sulfur (S) Formation of calcium sulfide and hydrogen chloride CaCl2+ H2S   react and convert into  CaS + 2HCl
Phosphorus (P) Formation of calcium phosphate 3 CaCl2 + 2Na3PO4   react and convert into  Ca3(PO4)2 + 6NaCl
Selenium (Se) Formation of calcium selenide and hydrogen chloride CaCl2+ H2Se   react and convert into  CaSe + 2HCl
Tellurium (Te) Formation of calcium telluride and hydrogen chloride CaCl2+ H2Te   react and convert into  CaTe + 2HCl

Reaction of calcium chloride with Metalloid

Metalloid Reaction with Calcium Chloride Reaction equation
Boron (B)   no product
Silicon (Si) Formation of calcium silicide and hydrogen chloride gas CaCl2+ Si   react and convert into  CaSi + 2Cl2(g) + H2(g)
Germanium (Ge) Formation of calcium germanide and hydrogen chloride gas CaCl2+ Ge   react and convert into  CaGe + 2Cl2(g) + H2(g)
Arsenic (As) Formation of calcium arsenide and hydrogen chloride gas CaCl2+ As   react and convert into  CaAs + 2Cl2(g) + H2(g)
Antimony (Sb) Formation of calcium antimonide and hydrogen chloride gas CaCl2+ Sb   react and convert into  CaSb + 2Cl2(g) + H2(g)
Tellurium (Te) Formation of calcium telluride and hydrogen chloride gas CaCl2+ H2Te   react and convert into  CaTe + 2HCl

Reaction of calcium chloride with Lanthanide

Lanthanide Reaction with Calcium Chloride Reaction equation
Cerium (Ce) Formation of cerium(III) chloride CeCl3 + 3 CaCl2   react and convert into  3CaCl2CeCl3
Praseodymium (Pr) Formation of praseodymium(III) chloride PrCl3 +3 CaCl2  react and convert into  3CaCl2PrCl3
Neodymium (Nd) Formation of neodymium(III) chloride NdCl3 + 3 CaCl2   react and convert into  3CaCl2NdCl3
Samarium (Sm) Formation of samarium(III) chloride SmCl3 + 3 CaCl2   react and convert into  3CaCl2SmCl3
Europium (Eu) Formation of europium(III) chloride EuCl3 + 3 CaCl2   react and convert into  3CaCl2EuCl3
Gadolinium (Gd) Formation of gadolinium(III) chloride GdCl3 + 3 CaCl2   react and convert into  3CaCl2GdCl3
Terbium (Tb) Formation of terbium(III) chloride Tb Cl3+ 3 CaCl2   react and convert into  3CaCl2TbCl3
Dysprosium (Dy) Formation of dysprosium(III) chloride DyCl3 + 3 CaCl2   react and convert into  3CaCl2DyCl3
Holmium (Ho) Formation of holmium(III) chloride Ho Cl3 + 3 CaCl2   react and convert into  3CaCl2HoCl3
Erbium (Er) Formation of erbium(III) chloride ErCl3 + 3 CaCl2  react and convert into  3CaCl2ErCl3
Thulium (Tm) Formation of thulium(III) chloride TmCl3 + 3 CaCl2   react and convert into  3CaCl2TmCl3
Ytterbium (Yb) Formation of ytterbium(III) chloride YbCl3 + 3 CaCl2   react and convert into  3CaCl2YbCl3
Lutetium (Lu) Formation of lutetium(III) chloride Lu Cl3 + 3 CaCl2   react and convert into  3CaCl2LuCl3

 

Reaction of calcium chloride with Actinide

 

Actinide Reaction with Calcium Chloride Reaction equation
Thorium (Th) Formation of thorium(IV) chloride ThCl4 + 2 CaCl2  react and convert into  2CaCl2ThCl4
Protactinium (Pa) Formation of protactinium(V) chloride PaCl5 + 5 CaCl2   react and convert into  5CaCl2PaCl5
Uranium (U) Formation of uranium(IV) chloride UCl4 + 2 CaCl2   react and convert into  2CaCl2UCl4
Formation of uranium(V) chloride UCl5 + 5 CaCl2   react and convert into  5CaCl2UCl5
Formation of uranium(VI) chloride UCl6 + 3 CaCl2   react and convert into  3CaCl2UCl6
Neptunium (Np) Formation of neptunium(IV) chloride NpCl4 + 2 CaCl2   react and convert into  2CaCl2NpCl4
Formation of neptunium(V) chloride NpCl5 + 5 CaCl2   react and convert into  5CaCl2NpCl5
Plutonium (Pu) Formation of plutonium(III) chloride PuCl3 + 3 CaCl2  react and convert into  3 CaCl2MdCl3
Formation of plutonium(IV) chloride PuCl4 + 2 CaCl2   react and convert into  2CaCl2PuCl4
Formation of plutonium(V) chloride PuCl5 + 5 CaCl2   react and convert into  5CaCl2PuCl5
Americium (Am) Formation of americium(III) chloride AmCl3 + 3 CaCl2   react and convert into  3 CaCl2MdCl3
Curium (Cm) Formation of curium(III) chloride CmCl3 + 3 CaCl2   react and convert into  3 CaCl2MdCl3
Californium (Cf) Formation of californium(III) chloride CfCl3 + 3 CaCl2   react and convert into  3 CaCl2MdCl3
Formation of californium(IV) chloride CfCl4 + 2 CaCl2   react and convert into  2CaCl2CfCl4
Formation of californium(VI) chloride CfCl6 + 3 CaCl2   react and convert into  3CaCl2CfCl6
Einsteinium (Es) Formation of einsteinium(III) chloride EsCl3 + 3 CaCl2   react and convert into  3 CaCl2MdCl3
Fermium (Fm) Formation of fermium(III) chloride FmCl3 + 3 CaCl2   react and convert into  3 CaCl2MdCl3
Mendelevium (Md) Formation of mendelevium(III) chloride MdCl3 + 3 CaCl2  react and convert into  3CaCl2MdCl3

 

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