Calcium Carbonate [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman | Last updated: February 3, 2024

The chemical formula of calcium carbonate is CaCO3.

Physical Properties of Calcium Carbonate:

Properties Details
Appearance White, odorless powder
Crystal Structure Hexagonal or trigonal
Density 2.71 g/cm³
Hardness 3 on the Mohs scale
Melting Point Decomposes at around 825°C (1517°F)
pH Basic (alkaline)
Refractive Index 1.59
Solubility Insoluble in water
State Solid

Chemical Properties of Calcium Carbonate:

Properties Details
Chemical Formula CaCO₃
Effervescence Calcium carbonate exhibits effervescence when reacted with acids
Hygroscopicity Calcium carbonate is slightly hygroscopic
Reaction with Acids Reacts with acids to produce carbon dioxide and a salt
Reaction with Carbon Dioxide Reacts with carbon dioxide to form calcium bicarbonate
Reaction with Heat Decomposes upon heating to form calcium oxide and carbon dioxide
Reaction with Water Insoluble in water
Reactivity with Other Metals Calcium carbonate reacts with certain metals to form corresponding metal carbonates
Reactivity with Oxidizing Agents It can react with strong oxidizing agents
Thermal Decomposition Decomposes at high temperatures to form calcium oxide and carbon dioxide

Reaction Of Calcium Carbonate

Alkali Metal

Alkali Metal Reaction with Calcium Carbonate
Lithium (Li) 2Li + CaCO3 react and changes into Li2CO3 + Ca
Sodium (Na) 2Na + CaCO3 react and changes into Na2CO3 + Ca
Potassium (K) 2K + CaCO3 react and changes into K2CO3 + Ca
Rubidium (Rb) 2Rb + CaCO3 react and changes into Rb2CO3 + Ca
Cesium (Cs) 2Cs + CaCO3 react and changes into Cs2CO3 + Ca

 

Alkaline Earth Metal

 

Alkaline Earth Metal Reaction with Calcium Carbonate
Beryllium (Be) No reaction with calcium carbonate
Magnesium (Mg) Mg + CaCO3 react and changes into MgCO3 + Ca
Calcium (Ca) CaCO3 + Ca react and changes into 2CaO + CO2
Strontium (Sr) Sr + CaCO3 react and changes into SrCO3 + Ca
Barium (Ba) Ba + CaCO3 react and changes into BaCO3 + Ca

 

Transition Metal

Transition Metal Reaction with Calcium Carbonate
Scandium (Sc) No reaction with calcium carbonate
Titanium (Ti) Ti + 2CaCO3 react and changes into TiO2 + 2CaO + 2CO2
Vanadium (V) 2V + 5CaCO3 + 11/2O2 react and changes into 2V2O5 + 5CaO + 5CO2
Chromium (Cr) 2Cr + 3CaCO3 + 2O2 react and changes into 2Cr2O3 + 3CO2 + 3CaO
Manganese (Mn) 2Mn + 3CaCO3 + 2O2 react and changes into 2MnO2 + 3CO2 + 3CaO
Iron (Fe) 2Fe + 3CaCO3 + 2O2 react and changes into 2FeO + 3CO2 + 3CaO

 

 

Non-Transition Metal

 

Non-Transition Metal Reaction with Calcium Carbonate
Boron (B) No reaction with calcium carbonate
Carbon (C) CaCO3 + 2HCl react and changes into CaCl2 + CO2 + H2O
Nitrogen (N) No reaction with calcium carbonate
Oxygen (O) 2CaCO3 + 2SO2 + O2 react and changes into 2CaSO4 + 2CO2
Fluorine (F) No reaction with calcium carbonate
Neon (Ne) No reaction with calcium carbonate
Aluminum (Al) 2Al + 3CaCO3 + 3H2O react and changes into Al2O3 + 3CO2 + 3Ca(OH)2
Silicon (Si) No reaction with calcium carbonate
Phosphorus (P) No reaction with calcium carbonate
Sulfur (S) CaCO3 + 2H2SO4 react and changes into CaSO4 + H2O + CO2 + SO2
Chlorine (Cl) CaCO3 + 2HCl react and changes into CaCl2 + CO2 + H2O

Non-Metal

 

Non-Metal Reaction with Calcium Carbonate
Hydrogen (H) CaCO3 + 2HCl react and changes into CaCl2 + CO2 + H2O
Helium (He) No reaction with calcium carbonate
Boron (B) No reaction with calcium carbonate
Carbon (C) CaCO3 + 2HCl react and changes into CaCl2 + CO2 + H2O
Nitrogen (N) No reaction with calcium carbonate
Oxygen (O) 2CaCO3 + 2SO2 + O2 react and changes into 2CaSO4 + 2CO2
Fluorine (F) No reaction with calcium carbonate
Neon (Ne) No reaction with calcium carbonate
Phosphorus (P) No reaction with calcium carbonate
Sulfur (S) CaCO3 + 2H2SO4 react and changes into CaSO4 + H2O + CO2 + SO2
Chlorine (Cl) CaCO3 + 2HCl react and changes into CaCl2 + CO2 + H2O

Metalloid

 

Metalloid Reaction with Calcium Carbonate
Boron (B) No reaction with calcium carbonate
Silicon (Si) No reaction with calcium carbonate
Germanium (Ge) No reaction with calcium carbonate
Arsenic (As) As2O3 + 3CaCO3 + 3C react and changes into 2As + 3CO2 + 3CaO
Antimony (Sb) No reaction with calcium carbonate
Tellurium (Te) No reaction with calcium carbonate

 

 

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