Dry ice [Chemical formula, Physical, Chemical Properties and Reactions]

By: Prof. Dr. Fazal Rehman Shamil | Last updated: February 3, 2024

Dry ice have chemical formula known as CO2.

Physical Properties of Dry Ice:

Properties Details
AppearanceSolid white or colorless blocks or pellets
Boiling Point-78.5°C (-109.3°F)
ConductivityPoor conductor of heat and electricity
Density1.56 g/cm³ (solid)
Melting Point-78.5°C (-109.3°F)
OdorNo distinctive odor
SolubilityInsoluble in water
StateSolid at standard temperature and pressure
Sublimation Point-78.5°C (-109.3°F)
Vapor Pressure1 atm at -78.5°C (-109.3°F)

Chemical Properties of Dry Ice:

Properties Details
Acid/Base PropertiesAcidic when dissolved in water, forms carbonic acid (H2CO3)
Chemical FormulaCO2 (carbon dioxide)
FlammabilityNon-flammable
pHSlightly acidic when dissolved in water
Reaction with MetalsDoes not react with most metals
Reaction with WaterSublimes directly to gas when exposed to water
ReactivityNon-reactive with most common substances
ToxicityNon-toxic in small quantities, can cause asphyxiation in high concentrations

Reactions of dry ice with Alkali Metal

Alkali MetalReaction with Dry Ice (CO2)
Lithium (Li)  no product formed among dry ice and lithium metal.
Sodium (Na)Sodium metal counters  with dry ice   and    resulting product →  sodium carbonate (Na2CO3).
Potassium (K)Potassium metal counters  with dry ice   and    resulting product →  potassium carbonate (K2CO3).
Rubidium (Rb)Rubidium metal counters  with dry ice   and    resulting product →  rubidium carbonate (Rb2CO3).
Cesium (Cs)Cesium metal counters  with dry ice   and    resulting product →  cesium carbonate (Cs2CO3).
Francium (Fr) No reaction

Reactions of dry ice with Alkaline Earth Metal

Alkaline Earth MetalReaction with Dry Ice (CO2)
Beryllium (Be)  no product formed among dry ice and beryllium metal.
Magnesium (Mg)  no product formed among dry ice and magnesium metal.
Calcium (Ca)  no product formed among dry ice and calcium metal.
Strontium (Sr)  no product formed among dry ice and strontium metal.
Barium (Ba)  no product formed among dry ice and barium metal.
Radium (Ra)  no product formed among dry ice and radium metal.

Reactions of dry ice with Transition Metal

Transition MetalReaction with Dry Ice (CO2)
Iron (Fe)Fe + 2COreact and convert into FeO + 2CO
Copper (Cu)2Cu + CO2  react and convert into 2CuO + C
Nickel (Ni)  no product formed among dry ice and nickel metal.
Silver (Ag)4Ag + 3CO2  react and convert into 2Ag2O + 2CO + C
Gold (Au)  no product formed among dry ice and gold metal.
Zinc (Zn)  no product formed among dry ice and zinc metal

Reactions of dry ice with Non-Transition Metal

Non-Transition MetalReaction with Dry Ice (CO2)
Hydrogen (H)  no product formed among dry ice and hydrogen gas.
Aluminum (Al)  no product formed among dry ice and aluminum metal.
Gallium (Ga)  no product formed among dry ice and gallium metal.
Silicon (Si)  no product formed among dry ice and silicon.
Phosphorus (P)  no product formed among dry ice and phosphorus.
Sulfur (S)  no product formed among dry ice and sulfur.
Chlorine (Cl)  no product formed among dry ice and chlorine gas.
Bromine (Br)  no product formed among dry ice and bromine liquid.