Which of the following is not a first order reaction?

Question: Which of the following is not a first order reaction?

A   Decomposition of H2​O2​
B   Decomposition of N2​O

C   Decomposition of N2​O5

D   Decomposition of SO2​Cl2​

Answer:  Decomposition of N2​O

 

Aspect Description
Reaction Order First order
Rate Law Expression A → Products

Rate = k[A] where [A] is the concentration of reactant A

Rate Constant (k) Positive constant that depends on the specific reaction
Dependence on Concentration The rate of the reaction is directly proportional to the concentration of the reactant (A)
Half-life t1/2 = (0.693 / k)
Units of Rate Constant (k) Depends on the overall reaction order
Examples

 

 

 

 

 

 

·        Decomposition of SO2Cl2

SO2Cl2 → Cl2 + SO2

Rate = k[SO2Cl2]

·        Decomposition of N2O5

2N2O5 → O2 + 4NO2

Rate = k[N2O5]

·        Decomposition of H2O2

2H2O2 → 2H2O + O2

Rate = k[H2O2]